ALUMINUM CHLORINE BATTERY

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ALUMINUM CHLORINE BATTERY ( aluminum-chlorine-battery )

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I ~ THEALUMINUMELECTRODE............... 31 Experimental . . . . . . . . . . . . . . . . . . . . . . 31 1 . c FEASIBILITYTESTOFAl/C12 CELL ............. 51 REFERENCES ...................... 55 Table of Contents Section No. . SUMMARY ........................ 1 INTRODUCTION ..................... 2 ALUMINUM CHLORIDE-ALKALI HALIDEMELTS ..................... 5 P r o p e r t i e s o f Mt h e e l t s . . . . . . . . . . . . . . . . . 5 Preparation and Purificationof A1Cl3-KC1-NaC1 Melts . . . . . . . . . . . . . . . . . 9 THECHLORINEELECTRODE ............... 1C? ExperimCenetlall ................... 19 S t a b i l i t y o f C a r b Eo nl e c t r o d e s . . . . . . . . . . . . . . . 1 9 Reduction of Chlorine on Smooth Virreous CaErbleocntrodes ................... 22 Conclusions ...................... 28 R e s uDl it s s c au ns ds i o n ................. 33 EffectofPotentialandTime ................ 33 AnodiBcehavior .............:..... 33 CathodicBehavior ................... 40 EffectofMeltComposition ............... 40 EffectofTemperature ................. 41 Effect of Current on Activation Polarization . . . . . . . . 42 i=onclusions ....................... 49 iii

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