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be possible to obtain a cell operable at even lower temperaturesby using as electrolyte a melt ofA1C13 with one or more of the other alkali chlorides (LiC1, RbC1,CsC1) which are all lower melting than NaCl or KCl. The theoretical energy densityof 650 W-hr/lb for the A1-C12 system compares favorablywith that of 754 W-hr/lb for the Li-CuF2 (propylene carbonate) system and990 W-hr/lb for the Li-C12 (molten salt) system. Another advantage of the A1-C12 system would be that solid A1 is easier to handle and much less hazardous than molten Li or Na. The hazards of the C12 electrode (common to both the Li-C12 and the proposed new system) will be reduced to some extent by the lower working temperatures; the same methods suggested for this electrode in the high temperature.cell (adsorption and occlusionon porous carbon or graphite) canbe used here. To devise a practical, workable cell, more knowledge is required of the reactions that take place at the anode and cathoodfe the particular system, as well as a knowledge of the electrolyte properues and of the interaction of the complete system. In addition to demonstrating the feasibilityof this kind of battery, it is our aim to optimize it and to definiets limitations by determining the kinetic parameters of the electrodes and the pertinent physico-chemical data of the electrolyte. 3PDF Image | ALUMINUM CHLORINE BATTERY
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