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Chlorine Characteristics

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Chlorine Characteristics ( chlorine-characteristics )

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Copyright © Tarek Kakhia. All rights reserved. http://tarek.kakhia.org Caustic handling , evaporation , storage and loading Caustic, fed to the cell room flows in a loop that is simultaneously bled off to storage with a part diluted with deionized water and returned to the cell line for strengthening within the cells. The caustic exiting the cell line must be monitored for strength, to maintain safe concentrations. Too strong or too weak a solution may damage the membranes. Membrane cells typically produce caustic in the range of 30% to 33% by weight. The feed caustic flow is heated at low electrical loads to control its exit temperature. Higher loads require the caustic to be cooled, to maintain correct exit temperatures . The caustic exiting to storage is pulled from a storage tank and may be diluted for sale to customers who require weak caustic or for use on site. Another stream may be pumped into a multiple effect evaporator set to produce commercial 50 % caustic. Rail cars and tanker trucks are loaded at loading stations via pumps. Hydrogen handling : Hydrogen produced may be vented unprocessed directly to the atmosphere or cooled, compressed and dried for use in other processes on site or sold to a customer via pipeline, cylinders or trucks. Some possible uses include the manufacture of hydrochloric acid or hydrogen peroxide, as well as desulfurization of petroleum oils, or use as a fuel in boilers or fuel cells. In Porsgrunn the byproduct is used for the hydrogen fueling station at Hynor. Energy consumption : Production of chlorine is extremely energy intensive . Energy consumption per unit weight of product is not far below that for iron and steel manufacture and greater than for the production of glass or cement . Since electricity is an indispensable raw material for the production of chlorine, the energy consumption corresponding to the electrochemical reaction cannot be reduced. Energy savings arise primarily through applying more efficient technologies and reducing ancillary energy use. 13

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