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5. Alagia, M.; Balucani, N.; Cartechini, L.; Casavecchia, P.; vanKleef, E. H.; Volpi, G. G.; Aoiz, F. J.; Banares, L.; Schwenke, D. W.; Allison, T. C.; Mielke, S. L.; Truhlar, D. G., Dynamics of the simplest chlorine atom reaction: An experimental and theoretical study. Science 1996, 273 (5281), 1519-1522. 6. Li, L. Y.; Kim, S.; Wang, W.; Vijayakumar, M.; Nie, Z. M.; Chen, B. W.; Zhang, J. L.; Xia, G. G.; Hu, J. Z.; Graff, G.; Liu, J.; Yang, Z. G., A Stable Vanadium Redox-Flow Battery with High Energy Density for Large-Scale Energy Storage. Adv. Energy Mater. 2011, 1 (3), 394-400. 7. Vijayakumar, M.; Wang, W.; Nie, Z. M.; Sprenkle, V.; Hu, J. Z., Elucidating the higher stability of vanadium(V) cations in mixed acid based redox flow battery electrolytes. J. Power Sources 2013, 241, 173-177. 8. Kim, S.; Thomsen, E.; Xia, G. G.; Nie, Z. M.; Bao, J.; Recknagle, K.; Wang, W.; Viswanathan, V.; Luo, Q. T.; Wei, X. L.; Crawford, A.; Coffey, G.; Maupin, G.; Sprenkle, V., 1 kW/1 kWh advanced vanadium redox flow battery utilizing mixed acid electrolytes. J. Power Sources 2013, 237, 300-309. 9. Yang, Y. D.; Zhang, Y. M.; Liu, T.; Huang, J., Improved broad temperature adaptability and energy density of vanadium redox flow battery based on sulfate-chloride mixed acid by optimizing the concentration of electrolyte. J. Power Sources 2019, 415, 62-68. 10. Lee, J.; Muya, J. T.; Chung, H.; Chang, J., Unraveling V(V)-V(IV)-V(III)-V(II) Redox Electrochemistry in Highly Concentrated Mixed Acidic Media for a Vanadium Redox Flow Battery: Origin of the Parasitic Hydrogen Evolution Reaction. ACS Appl. Mater. Interfaces 2019, 11 (45), 42066-42077. 11. Kim, S.; Vijayakumar, M.; Wang, W.; Zhang, J.; Chen, B.; Nie, Z.; Chen, F.; Hu, J.; Li, L.; Yang, Z., Chloride supporting electrolytes for all-vanadium redox flow batteries. Phys. Chem. Chem. Phys. 2011, 13 (40), 18186-93. 12. Gibson, S. In Arlington Microgrid Project, Energy Storage Safety and Reliability Forum, Richland, WA/ Virtual, Richland, WA/ Virtual, 2022. 13. Flatt, C.; Sullivan, L. The U.S. made a breakthrough battery discovery - then gave the technology to China. https://www.npr.org/2022/08/03/1114964240/new-battery-technology- china-vanadium (accessed 08/03/2022). 14. Pourbaix, M., Atlas of Electrochemical Equilibria in Aqueous Solutions. National Association of Corrosion Engineers: Houston, Texas, 1974; p 648. 15. Lourenssen, K.; Williams, J.; Ahmadpour, F.; Clemmer, R.; Tasnim, S., Vanadium redox flow batteries: A comprehensive review. J. Energy Storage 2019, 25. 16. Bard, A. J.; Faulkner, L. R., Electrochemical Methods: Fundamentals and Applications. 2nd ed.; John Wiley and Sons, Inc: 2001. 17. Nielsen, H. P.; Frandesen, F. J.; Dam-Johansen, K.; Baxter, L. L., The implications of chlorine-associated corrosion on the operation of biomass-fired boilers. Prog. Energy Combust. Sci. 2000, 26, 283-298. 18. Pelucchi, M.; Frassoldati, A.; Faravelli, T.; Ruscic, B.; Glarborg, P., High-temperature chemistry of HCl and Cl2. Combust. Flame 2015, 162 (6), 2693-2704. 19. Lifshitz, A.; Schechner, P., The Mechanism of the H2 + Cl2 Reaction: Ignition Behind Reflected Shocks. Int. J. Chem. Kinet. 1975, 7, 125-142. 20. Lee, J. H.; Knystautas, R.; Guiao, C.; Bekesy, A.; Sabbagh, S., On the Instability of H2- Cl2 Gaseous Detonations. Combust. Flame 1972, 18, 321-325. 14PDF Image | Chlorine Gas Generation in Mixed-Acid Vanadium Redox
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