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Development of the Zinc-Chlorine Battery for Utility

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Development of the Zinc-Chlorine Battery for Utility ( development-zinc-chlorine-battery-utility )

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These observations, although encouraging, are speculative. It is necessary for this and other on-going studies to provide more definitive data upon which final conclusions may be based. RAMIFICATIONS OF CHLORINE ELECTRODE DEGRADATION Corrosive degradation of the porous-graphite chlorine electrode can result in cell failure in numerous ways. Those considered of major significance are detailed in Table 28-2. Table 28-2 POSSIBLE CHLORINE ELECTRODE FAILURE MODES Failure 1. "Bowing" of electrode 2. Crack (or rupture) 3. Loss of "active" surface 4. Electrode-to-bus contact deterioration 5. Non-uniform electrolyte flow 6. Non-uniform electrolyte flow Cause Corrosive weakening Corrosive weakening Corrosion, or corrosive undercutting Corrosion Uneven corrosion Plugging of electrode back­ side with debris Manifested as: Lowered capacity due to decreased gap. (Shorting possible). Decreased voltaic perfor­ mance (no longer "flow­ through) . Shorting may occur. Zinc corrosion. Decreased voltaic perfor­ mance. Decreased voltaic perfor­ mance . Deterioration in discharge voltage profile. Deterioration in discharge voltage profile. For discussion purposes two "types" of failure are categorized as follows: ® Loss of physical integrity (1 and 2) of the electrode plate due to corrosion resulting in what can be total failure of a cell. ® Decreases in voltaic performance (3 through 6) which will be gradual and of varying degree. 28-6

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