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The pH change of the three solutions was recorded as 6M HCI was added in small incre ments. The use of 6M HCI was dictated by the desire to minimize volume expansion. The pH curves for these three solutions are shown in Figure 30-4. 400.0 300.0 200.0 90.0 80.0 70.0 60.0 50.0 Q 30.0 20.0 ELECTROLYTE COMPOSITION H X - 2.06 MOLAL ZnCl2 + 3.17 MOLALNaCl Y Z - 2.06 MOLAL ZnCl2 - 2.06 MOLAL ZnCl2 3.17 MOLAL KC1 Plot of pH of ZnCl2 Figure 30-4. solutions as a function of free acid concentration in the presence of a supporting electrolyte. DISCUSSION Solutions of zinc chloride are acidic due to the hydrolysis of the zinc ion. Bieder- man (30-2), Schorsch (30-3), and Perrin (30-4) have evaluated the hydrolysis of zinc 30-6PDF Image | Development of the Zinc-Chlorine Battery for Utility
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