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For the partial molal volumes of salt solutions shown in Figure 30-5, density vs. composition tables found in the 42nd edition of Handbook of Chemistry and Physics (published by CRC) were used. Several different techniques may be used to calculate v2. following equation was used (30-5). M2~1000 (3D/3c) V2 - D-c (3D/3c) where In this work, the v2 = partial molal volume of the solute M2 = molecular weight of the solute D = density, g/ml c = concentration in moles/liter In Figure 30-5, the concentration intervals were about 0.1 molar for zinc chloride while for potassium chloride and sodium chloride, the concentration intervals ex tended to about 0.3 - 0.5 molar. ZnCI2 O •■4-.. ..... i • '4...— ...... i.. 12345 CONCENTRATION — moles/liter Figure 30-5. Plot of calculated partial molal volumes of battery electrolyte salts. 30-9PDF Image | Development of the Zinc-Chlorine Battery for Utility
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