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Development of the Zinc-Chlorine Battery for Utility

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Development of the Zinc-Chlorine Battery for Utility ( development-zinc-chlorine-battery-utility )

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INTRODUCTION Section 31 CURRENT DISTRIBUTION IN ZINC-CHLORINE BATTERIES The heart of the zinc-chlorine battery system, as presently envisioned, is the comb-type bipolar battery stack shown schematically in Figure 31-1. The intercell bus bar, fabricated of graphite, serves not only to electrically connect adjacent unit cells but also to separate the individual cell electrolytes. Zinc-electrode substrates, also fabricated of graphite, are fitted into grooves on one side of the bus bar. Similarly, pairs of chlorine-electrode -substrates are fitted into grooves on the other side of the bus bar. During charge and discharge, electro­ lyte is pumped through the chlorine-electrode substrates, which are fabricated of porous graphite. This comb assembly of chlorine-electrode substrates, bus bar, and zinc-electrode substrates is replicated to form the series-connected stack shown in Figure 31-1. Stack termination is accomplished, as shown, by use of a bus UNIT CELL ZINC / ELECTRODE Figure 31-1. Comb-type bipolar arrangement of electrodes in a zinc-chlorine battery. 31-1

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