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Development of the Zinc-Chlorine Battery for Utility

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Development of the Zinc-Chlorine Battery for Utility ( development-zinc-chlorine-battery-utility )

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CHLORINE SUS llr ill ELECTROLYTE Cl2 —DEPLETED ELECTROLYTE 4j44''lrl'4; FULLY DISCHARGED CHARGING Zn BUS DISCHARGING FULLY CHARGED Figure 31-2. Sequence of schematics showing the distribution of zinc on the zinc-electrode substrate during a full-'charge- discharge cycle. thickness distribution after a seven-hour charge under standard case conditions is presented. The result of these calculations are then contrasted with each other and with experimental data on weight distribution across the width of the zinc electrodes. CELL MODEL The comb-type bipolar unit cell is comprised of a number of single cells connected in parallel. This repetition allows for the development of the electrical-circuit model of the cell from a single-cell section. First, a discussion of the voltaic losses in the single cell and the assumptions made regarding these losses is pre­ sented. The terminology used in this discussion and throughout the paper is shown in Table 31-1. Figure 31-3 illustrates a top view of the single-cell section of a unit cell. The various voltage losses are identified. A voltage loss in the bus bar, V , is found on each side of the cell, as the current enters and exits the cell. From symmetry 31-3

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