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Development of the Zinc-Chlorine Battery for Utility

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Development of the Zinc-Chlorine Battery for Utility ( development-zinc-chlorine-battery-utility )

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Figure 31-10 illustrates the effect of variations in the chlorine-electrode resis­ tivity-thickness ratio on current density. Again, the zinc-electrode current den­ sity at the chlorine bus is used as a reference, as it serves to indicate the sen­ sitivity of the parameter variations on current density. The graph reveals that an essentially linear relationship exists between the current density at the chlo­ rine bus and the chlorine-electrode resistivity-thickness ratio. 54 - > 48 Z 44 CC 34 STANDARD CASE CHLORINE-ELECTRODE RESISTIVITY-THICKNESS RATIO thickness ratio, Pg/<5g, —ohm Figure 31-10. Active cell current density adjacent to the chlorine electrode bus as a function of the chlorine-electrode resistivity-thickness ratio. Figure 31-11 shows the effect of the compound resistivity-gap product on current density at the chlorine bus. It is clear from this curve that the effect of this parameter on the current-density distribution is significant. This parameter is of course the most susceptible to physical variation. Even a simple temperature change in the electrolyte will cause a change in the compound resistivity, p^_. Although the current-density distribution curve in Figure 31-7 may be smoothed or leveled by an increase in p *6 , this will also increase the voltaic losses in the te 31-18 10o

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