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Development of the Zinc-Chlorine Battery for Utility

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Development of the Zinc-Chlorine Battery for Utility ( development-zinc-chlorine-battery-utility )

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TIME — minutes Figure 3, The potentials of the CI2 and Zn electrodes vs. the Zn reference electrode during the charging. Electrolyte: Temperature: Total Current: Apparent current density: Reference electrode: ZnCl2 (2M) 25°C 3 A 44mA/cm2 Zn Zn electrode is very small, below -50 mV during charging and below +40 mV during discharging. The overpotential on the Cl^ electrode is +100 mV and -200 mV during charging and discharging, respectively. By adding KC1 (2M) and NaCl (2M) as supporting electrolytes, the ohmic drop was reduced significantly and the over­ all cell potential was reduced to 2.20 V during the charging and increased to 1.90 V during the discharging. The voltaic performance of the cell improved by adding KC1 both during charging and discharging; however, the addition of NaCl lowered only the charging voltage, but did not improve the discharging voltage as expected from conductance measurements. A-7

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