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Electrochemistry Electrolysis of Aqueous Salts • Sulfate – SO42– • Nitrate – NO3– • Chloride – Cl– • Bromide – Br– • Iodide – I– • Hydroxide – OH– • Not oxidised during electrolysis of the aqueous salt. • Oxidised only if the aqueous solution is concentrated, e.g. a concentrated solution of sodium bromide. • The hydroxide ion is readily oxidised at the anode. 4OH–(aq) → 2H2O(l) + O2(g) + 4e– Ions Are More Easily OxidisedPDF Image | Electrolysis of Aqueous Salts
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