Electrolysis of Aqueous Salts

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Electrolysis of Aqueous Salts ( electrolysis-aqueous-salts )

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Electrochemistry Electrolysis of Aqueous Salts • Electrolysis of an aqueous salt. → If the aqueous solution is dilute, or it contains the salt of a nitrate or sulfate, then hydroxide ions are preferentially oxidised at the anode to produce oxygen gas and water: 4OH–(aq) → O2(g) + 2H2O(l) + 4e– → If the aqueous solution is a concentrated solution of either a chloride, bromide or iodide, then the chloride, bromide or iodide ions are preferentially oxidised at the anode to produce the Group 17 element: 2X–(aq) → X2(aq) + 2e–

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