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Electrolysis of Molten Substances What does it form? Molten ionic compounds can be electrolysed because the ions can move freely and conduct electricity. At the cathode, positive metal ions are reduced to metal atoms. At the anode, negative ions are oxidised to atoms or molecules. Molten ionic compounds are always broken up into their elements. Anode Cathode +- Pb2+ Br- Pb2+ Br- Cathode: You will see silver liquid as molten lead is formed. Pb2+ + 2e- Pb This is the half equation – you need to balance the charges and electrons to form atoms Anode: You will see brown vapour as bromine gas is formed. 2Br- Br2 + 2e- This is the half equation –as bromine is diatomic – you need to balance with 2 bromine ions.PDF Image | How to work with Electrolysis
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