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MANUFACTURE OF CHEMICALS BY ELECTROLYSIS

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MANUFACTURE OF CHEMICALS BY ELECTROLYSIS ( manufacture-chemicals-by-electrolysis )

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ELECTEOLYTIC HYDROGEN AND OXYGEN. OZONE 15 from the edge of which an asbestos sack diaphragm hangs to prevent mixing of the gases. Cells of the filter-press type have been developed during recent years. The Inter- 1 national Oxy-Hydric Company of Chicago makes a cell of this pattern in which the electrodes, corrugated to in- crease their surface, are constructed of special alloy heavily nickel-plated. The electrolyte employed is 20 per cent, caustic potash, and asbestos diaphragms are used. Oxygen is generated, of 99'5 per cent, purity, at the rate of 4 cubic feet per K.W.H. Other plant of this type is made by 2 L'Oxyhydrique Fran9aise and by Messrs. Eycken, Leroy 8 & Moritz. The following cells of various patterns for producing hy- drogen and oxygen have been patented during the last few years,but many of them still await industrial development:— Cell of Siemens Bros. & Obach, Eng. Pat. 11973 (1893). 4 A cell devised by K J.'Vareille in which the gases are effectively separated by a system of V-shaped troughs which completely divide cathodes from anodes. The cell of Fischer, Leuning & Collins described in U.S. Pat. 1004249 (1911). The Tommasini System, U.S. Pat. 1035060 (1912). The Burdett System, U.S. Pat. 1086804 (1914). ELECTEOL YTIO PEODUCTION OF OZONE. During the electrolysis of dilute sulphuric acid a con- siderable amount of ozone is mixed with the oxygen evolved 1 Met.andChem.Eng.,1916,14,288. 2Fr.Pat# 459967(1912). tlbid. 397319 (1908), U.S. Pat., 603058. *Ibid. 355652 (1905).

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