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NASA Redox Storage System Development Project 1980

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NASA Redox Storage System Development Project 1980 ( nasa-redox-storage-system-development-project-1980 )

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-100 -50 < e ,.J c: e... ::> (,,) 50 Bmb 0 -1o -10 -1 Voltage, V (a) Uncatalyzed felt (b) .. Best" electrode ( 05 MCrCI3, 2MHCIl. (Io-4 MPbCIZ' 2 MHCI o(!j MCrCI31 (el Poor electrode (good chromIum actIvity, excessive hydrogen evolutIon) B c: ~o )-\\ \I \I\ .lS II \ \\ ''''\ \\ ;1/ \\\If'.\\ < ~/ ~// A\\ "- /11; \ \ \ I;.' \ , \ \jl;~ \ \'\t:l' '-.. \ ' I , I . \ I \,\..\--...... (b) (c) FIgure 29 - Cyclic voltammetry of carbon feH electrodes Scan rate, 10 mV/s; felt area, Zcm2, felt thickness, 0 2D3 to 0 229 cm, all potentials versus AgCI electrode VIolet , . \ ,rYeIJow Blue IGreenIII·· Red] ''-Orange Cr1H20)4 CIZ+l Cr1Hz0ls CI+Z Cr1H20 l t 3 Cr+ 2 specIes I\ I\ I' '\, I\I\ '\I\ :'--' \ ,I ,\ ,I /~ . \. --". '"' I 350 400 450 500 55D 600 700 800 900 1000 Wavelength, nm Figure30 ..SpectraofchromiumcomplexIons \

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