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Regenerative Hydrogen Chlorine Fuel Cell for Grid-Scale

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Regenerative Hydrogen Chlorine Fuel Cell for Grid-Scale ( regenerative-hydrogen-chlorine-fuel-cell-grid-scale )

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of a fuel cell electrode is typically unacceptably low. Furthermore, a GDL is responsible for evenly transporting reactants from the flow channels to the catalyst layers. In principle, it is possible to achieve support by constantly maintaining a chlorine overpressure and to achieve lateral conductivity by embedding small cross-section conductors in the electrode, but these methods are unlikely to be implemented due to unnecessary complication and cost. In this model, we intend the mass transport modeling to represent a statistically- averaged behavior, understanding that the local real loss behavior on a complicated three- dimensional, porous electrode could lie to one side or the other of the mean mass transport loss computed here. We expect the conclusion of the model – that losses due to mass transport limitations are insignificant compared to other losses when the cell is operated at low current density for high efficiency – to be unchanged by future work involving three-dimensional mass transport. The model was used to evaluate cell potentials in both charge mode and discharge mode. For the majority of results presented in this paper, we omit the electrolytic, charge- mode behavior. Typically, a cell that shows good performance in discharge mode also shows good performance in charge mode (particularly within the confined concentration range used in this model), allowing us to simplify the presentation of the model results. 4

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