Chlorine Gas Generation in Mixed-Acid Vanadium Redox

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Chlorine Gas Generation in Mixed-Acid Vanadium Redox ( chlorine-gas-generation-mixed-acid-vanadium-redox )

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Supporting Information for Quantification of Chlorine Gas Generation in Mixed-Acid Vanadium Redox Flow Batteries Reed M. Wittman,1*, Cassandria Poirier2, Harry D. Pratt III3, Travis M. Anderson2, Yuliya Preger1 1 Energy Storage Technology and Systems, Sandia National Laboratories, 1515 Eubank Blvd SE, Albuquerque, New Mexico 87185, USA 2 Power Sources R&D, Sandia National Laboratories, 1515 Eubank Blvd SE, Albuquerque, New Mexico 87185, USA 3 Special Technologies, Sandia National Laboratories, 1515 Eubank Blvd SE, Albuquerque, New Mexico 87185, USA *Email: rwittm@sandia.gov Table of Contents 1. Experimental Conditions ................................................................................................... 17 1.1 Cell Assembly ........................................................................................................................... 17 1.2 Electrolyte Composition ........................................................................................................... 18 1.3 Cell Cycling ............................................................................................................................... 18 1.4 Gas Monitoring ........................................................................................................................ 19 2. Additional Cycling Data .................................................................................................... 20 2.1 Variable Current Experiment .................................................................................................... 20 2.3 Long-term Cycling Experiment.................................................................................................. 22 2.4 Potential Stepping Experiment ................................................................................................. 23 3. Influence of HCl Concentration on Formal Potential .......................................................... 24 4. Cl2 Consumption................................................................................................................ 26 5. Scaling to Larger Systems.................................................................................................. 27 6. References ........................................................................................................................ 28 16

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