Development of the Zinc-Chlorine Battery for Utility

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Development of the Zinc-Chlorine Battery for Utility ( development-zinc-chlorine-battery-utility )

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VENT TO HOOD SUMP CELL THERMOMETER FLOW METER ^ TEMPERATURE CONTROLLED WATER Cl2 SUPPLY Figure 34-3. chlorine electrodes. Note use of bypass line for temperature con­ trol. Cell shown in the comb-type found in Figure 34-1. With the demountable cell shown in Figure 34-2, a glass battery jar is employed as the electrolyte sump and cell holder. The operational system employed for both performance evaluation and electrolytic processing is shown in Figure 34-3. Chlorination on discharge was achieved by sparging into the sump. A bypass line/heat exchanger assembly insured precise temperature control. System auxiliaries contacting the electrolyte were exclusively of glass, Kynar, and Teflon with the exception of a rotameter float and micropump shafts of titanium. Figure 34-4 is a photographic reproduction of the combs employed in scaling up the electrolytic process. These are end combs from an 8.3kWh submodule. They were held together in a Kynar case as shown diagrammatically in Figure 34-5. This was then placed in a glass battery jar. Electrical contact was made to the cell with titanium bus bars bolted down onto the ATJ graphite zinc and chlorine buses. ELECTROLYTE PUMP Test system used to evaluate voltaic performance of 34-6

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