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Electrochemical Mechanism of Molten Salt Electrolysis

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Electrochemical Mechanism of Molten Salt Electrolysis ( electrochemical-mechanism-molten-salt-electrolysis )

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Materials 2022, 15, 3956 11 of 11 19. Sure, J.; Vishnu, D.S.M.; Schwandt, C. Electrochemical conversion of oxide spinels into high-entropy alloy. J. Alloy. Compd. 2019, 776, 133–141. [CrossRef] 20. Sure, J.; Vishnu, D.S.M.; Kim, H.K.; Schwandt, C. Facile electrochemical synthesis of nanoscale (TiNbTaZrHf)C high-entropy carbide powder. Angew. Chem. Int. Ed. 2020, 132, 11928–11933. [CrossRef] 21. Freidina, E.B.; Fray, D.J. Study of the ternary system CaCl2–NaCl–CaO by DSC. Thermochim. Acta 2000, 356, 97–100. [CrossRef] 22. Lair, D.C.V.; Cassir, M. CO2 electrochemical reduction into CO or C in molten carbonates: A thermodynamic point of view. Electrochim. Acta 2015, 160, 74–81. [CrossRef] 23. Weng, W.; Wang, M.Y.; Gong, X.Z.; Wang, Z.; Wang, D.; Guo, Z.C. Electrochemical reduction behavior of soluble CaTiO3 in Na3AlF6-AlF3 melt for the preparation of metal titanium. J. Electrochem. Soc. 2017, 164, D551–D557. [CrossRef] 24. Schwandt, C.; Alexander, D.; Fray, D.J. The electro-deoxidation of porous titanium dioxide precursors in molten calcium chloride under cathodic potential control. Electrochim. Acta 2009, 54, 3819–3829. [CrossRef] 25. Suzuki, R.O. Calciothermic reduction of TiO2 and in situ electrolysis of CaO in the molten CaCl2. J. Phys. Chem. Solids 2005, 66, 461–465. [CrossRef] 26. Weng, W.; Wang, M.; Gong, X.; Wang, Z.; Guo, Z. Thermodynamic analysis on the direct preparation of metallic vanadium from NaVO3 by molten salt electrolysis. Chin. J. Chem. Eng. 2016, 24, 671–676. [CrossRef] 27. Hu, Y.J.; Wang, X.; Xiao, J.S.; Hou, J.G.; Jiao, S.Q.; Zhu, H.M. Electrochemical behavior of silicon (IV) ion in BaF2-CaF2-SiO2 melts at 1573 K. J. Electrochem. Soc. 2013, 160, D81–D84. [CrossRef] 28. Nicholson, R.S.; Shain, I. Theory of stationary electrode polarography. single scan and cyclic methods applied to reversible, irreversible, and kinetic systems. Anal. Chem. 1964, 36, 706–723. [CrossRef]

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