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Electrochemistry Electrolysis of Aqueous Salts • Electrolysis of an aqueous salt: → If the metal is above hydrogen in the electrochemical series, then hydrogen ions are preferentially reduced at the cathode to produce hydrogen gas: 2H+(aq) + 2e– → H2(g) → If the metal is below hydrogen in the electrochemical series, then metal ions are preferentially reduced at the cathode to produce the metallic element: Mn+(aq) + ne– → M(s)PDF Image | Electrolysis of Aqueous Salts
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