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MANUFACTURE OF CHEMICALS BY ELECTROLYSIS

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MANUFACTURE OF CHEMICALS BY ELECTROLYSIS ( manufacture-chemicals-by-electrolysis )

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26 THE MANUFACTURE OP CHEMICALS BY ELECTBOLYSIS 1 A cell used by the Salzbergwerke, Stassfurt, is shown in section in Fig. 7. It is of iron, and contains the solution of manganate, which is replenished by gradual solution of the fused product contained in the metal baskets B. The cathodes are immersed in cement boxes C which serve as diaphragms, and sheet iron anodes A dip into the liquor between the metal baskets and the cement cathode B B\ FIG. 7. compartments; 1 kilogram of permanganate requires about 0*7 K.W.H. and the voltage is about 2*8 volts. 2 The G-riesheim Elektron Company use a closed dia- phragm cell for preparing metallic permanganates, which is fitted with tubes for the escape of electrolytic gas. Their method for preparing the calcium salt is as follows : The cathode compartment contains caustic potash solution, and the anode compartment is j&lled with saturated manganate *D.R.P.101710 (1898), 2 J&R 145368(1904).

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