NASA Redox Storage System Development Project 1980

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NASA Redox Storage System Development Project 1980 ( nasa-redox-storage-system-development-project-1980 )

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0.186 0.771 C~O)6+3+ E-=Crf201t2 o75x10-5cm's C~O)5CI+2+ E-;:CrfH20~CI+1 l20x10-5cmls Rate of reduction of CrfH20)5 Cr21s 160times that of CrfH20)6+3 + (b) Figure27 -thermodynamicandkineticdataforcomplexedchromiumIonsatmercury electrodes Cell ~ I I I /\ "Counterelectrode \ Description of experiment: Instrument passes current between working electrode and counter electrode such that the potential between WOrking electrode and reference electrode Is varied at a controlled rate. Since no cu rrent Is passed th rough refe rence electrode, nopolarlzatloneffectsareproduced here. Thus the voltage-current curve Is cha racterlstlc of the working electrode only Ia) Reduction potentials versus H IH2 electrode. (b) Apparent electrochemical rate constants at equilibrium potential ..; Reference electrode..l I en Il Working electrode (feltl-i I JlI ~ -1 >0 11 Figure28 -Cyclicvoltammetry8Satoolforstudyingelectrodephenomena Time

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NASA Redox Storage System Development Project 1980

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