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64 CHAPTER4. RESULTSANDDISCUSSION 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 1.0 1cus 1br 2a 2b 3a 3b 4a 4b dopant position ∆E(Oc ) on Ru-doped TiO2 ∆E(Oc ) on Ti-doped RuO2 ∆E(Oc ) on DSA Optimal ∆E(Oc ) ∆E(Oc ) on pure TiO2 ∆E(Oc ) on pure RuO2 Figure 4.13: Oxygen adsorption energy trends, at 100% surface coverage, as the dopant atom position is varied in Ru-doped TiO2, Ti-doped RuO2 and in the DSA model system. The O adsorbate is allowed to adsorb on the “1cus” site in all cases, so that adsorption occurs directly on the dopant atom only in the “1cus” case. Figure reprinted from Karlsson et al. [16], with permission from Elsevier. Electronic adsorption energy / eVPDF Image | Studies of Electrode Processes in Industrial Electrosynthesis
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